WHOA. When you said chin and puns I thought we were talking chins of the double variety and puns of the fat-joke variety. That picture... shattered those expectations. I've never seen anything like that before in my life. She's actually really pretty other than her chin from another plane of reality.
What position is she applying for within the company? If she's looking to be an artist, she needs to make this look a whole hell of a lot better. If she did that, I could see this actually working. Otherwise, I doubt they're looking for new people for their creative staff, and I can't imagine this would get her a job doing any kind of programming. I could see their Promotions department maybe digging this, and the enthusiasm would probably be appealing to their Testing department. Cool, outside the box companies (like Valve) can really appreciate strange applications like this, it just needs to be... better.